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Date:2022-11-22MaterialsafetydatasheetMaterialSafetyDataSheetNameofproduct:HomeenergystoragesystemSampleName:ResidentialEnergyStorageSystemManufacturer:DaqinNewEnergyTechnology(Taizhou)Co.,LTDManufacturer:DaqinNewEnergyTech(Taizhou)Co.,Ltd.Date:2022-11-22MaterialsafetydatasheetMaterialSafetyDataSheet1.ChemicalsandcorporatelogosChemicalProductAndCompanyIdentificationSampleNameSampleNameHomeenergystoragesystemResidentialEnergyStorageSystemmodelModelTNK-10000-LV-A1productionunitManufactureDaqinNewEnergyTechnology(Taizhou)Co.,LTDDAQINNEWENERGYTECH(TAIZHOU).,LTD.AddressofproductionunitManufactureAddressNo.199,ScienceandTechnologyRoad,SanshuiStreet,JiangyanDistrict,TaizhouCity199KejiRoad,SanshuiStreet,JiangyanDistrict,TaizhouCityemergencytelephoneEmergencytelephonecall+86-523-885100622.OverviewofhazardsHazardsIdentificationHazardlabelfordangerousgoodsNinetypesoflithiumbatteriesClass9-LithiumbatteriesExplosivedangerExplosiveriskThisitemisnotanexplosivehazard.Thisarticledoesnotbelongtotheexplosiondangerousgoods.FlammablehazardFlammableriskThisitemisnotaflammabledangerousgoods.Thisarticledoesnotbelongtotheflammablematerial.HazardofoxidationOxidationriskThisitemisnotahazardousoxidant.Thisarticledoesnotbelongtotheoxidationofdangerousgoods.ToxicriskThearticleisnotatoxicdangerousgoods.Thisarticledoesnotbelongtothetoxicdangerousgoods.RadiationhazardRadioactiveriskThisitemisnotaradioactivedangerousgoods.Thisarticledoesnotbelongtotheradiationofdangerousgoods.CorrosionriskMordantriskThisitemisnotacorrosivedangerousgoods.Thisarticledoesnotbelongtothecorrosionofdangerousgoods.OtherrisksThebatterywatt-hourrate10.24kWhbelongstothelithiumionbattery.Watthourrate10.24kWh,whichbelongtotheLithium-ionbattery.Date:2022-11-223.Component/compositioninformationCompositionInformationingredientHazardouscomponentsPercentage/%Content/%CASNO.RemarkslithiumironphosphateLiFePO42615365-14-7–carbonCarbon127440-44-0–Electrolyte-hexafluorophosphoruslithium2421324-40-3–Electrolyte-solvent/–Polypropylene(PE)39003-07-0–copperCopper157440-50-8–aluminiumAluminum207429-90-5–4.FirstaidmeasuresFirstaidmeasureseyeIncaseofcontact,immediatelyrinsewithplentyofwaterforatleast15minutes,lifttheupperandlowereyelidsuntilthechemicalresiduedisappears,andseekmedicalattentionimmediately.EyeFlusheyeswithplentyofwaterforatleast15minutes,occasionallyliftingtheupperandlowereyelids.Getmedicalaid.skinIncaseofcontact,rinsewithplentyofwaterforatleast15minutes,removecontaminatedclothingandshoes,andseekmedicalattentionimmediately.SkinRemovecontaminatedclothesandrinseskinwithplentyofwaterorshowerfor15minutes.Getmedicalaid.inhalationMoveimmediatelyfromtheexposuretoafreshairplace,giveoxygenifbreathingisdifficult,andseekmedicalattentionimmediately.InhalationRemovefromexposureandmovetofreshairimmediately.Useoxygenifavailable.ingestionQuotetwoglassesofmilkorwater.Ifthepersonisstillconscious,inducevomitingandseekmedicalattentionimmediately.IngestionGiveatleast2glassesofmilkorwater.Inducevomitingunlesspatientisunconscious.Callaphysician6r7Date:2022-11-225.fireprotectionFire-fightingmeasuresIgnitionpoint:notapplicableFlashPoint:N/A.Autoignitiontemperature:notapplicableAuto-IgnitionTemperature:N/A.Fireextinguishingmedium:alargeamountofwater(cooling),carbondioxideExtinguishingMedia:Water,CO2.Specialfireextinguishingprocedure:self-containedbreathingapparatusSpecialFire-FightingProcedures:Self-containedbreathingapparatus.Abnormalfireorexplosion:Whenthecellisexposedtoanoverheatedenvironment,thesafetyvalvemayopen.UnusualFireandExplosionHazards:Cellmayventwhensubjectedtoexcessiveheat-exposingbatterycontents.Hazardoussubstancesproducedbycombustion:carbonmonoxide,carbondioxide,lithiumoxidefluegasHazardousCombustionProducts:Carbonmonoxide,carbondioxide,lithiumoxidefumes.6.LeakageemergencyhandlingAccidentalreleasemeasuresMeasurestakentopreventleakageorreleaseofbatterymaterialsIftheinternalmaterialsofthebatteryleak,immediatelyevacuatethetestareauntilthesmokedissipates.Opentheventilationsystemtodispersethehazardousgases.Cleanthetestareawithacloth,removeanyspilledliquids,placetheleakingbatteryinaplasticbag,andthenintoasteelcontainer.Avoidcontactwithskinoreyes,andavoidinhalingharmfulgases.StepstobeTakenincaseMaterialisReleasedorSpilledIfthebatterymaterialisreleased,removepersonnelfromareauntilfumesdissipate.Providemaximumventilationtoclearouthazardousgases.Wipeitupwithacloth,anddisposeofitinaplasticbagandputintoasteelcan.Thepreferredresponseistoleavetheareaandallowthebatterytocoolandvaporstodissipate.Providemaximumventilation.Avoidskinandeyecontactorinhalationofvapors.Removespilledliquidwithabsorbentandincinerate.WastedisposalmethodsItisrecommendedtocompletelydischargethebattery,consumethelithiummetalinsidethebattery,andburyitdeepinthesoil.WasteDisposalMethodItisrocommendedtodischargethebatterytotheend,touscupthemctallithiuminsidcthebattery,andtoburythedischargedbatteryinsoil.Question1Date:2022-11-227.Operation,handlingandstorageHandlingandstorageDonotopen,destroyorburnbatteries,astheymayexplode,burstorleakduringtheseprocesses.Donotovercharge,forcedischargeorthrowbatteriesintofire.Donotsqueezeorpuncturebatteriesorimmersetheminasolution.Thebatteryshouldnotbeopened,destroyedorincinerate,sincetheymayleakorruptureandreleasetotheenvironmenttheingredientsthattheycontaininthehermeticallysealedcontainer.Donotshortcircuitterminals,oroverchargethebattery,forcedover-discharge,throwtofire.Donotcrushorpuncturethebattery,orimmerseinliquids.Precautionsforoperation,handlingandstorageDonotabusethebatteryorelectricity,donotstorethebatteryathightemperature,itisbesttostorethebatteryinacool,dry,ventilatedenvironmentwithlittletemperaturechange.Donottouchthebatterywithheatingequipmentorexposethebatterydirectlytosunlight.PrecautionstobetakeninhandlingandstoringAvoidmechanicalorelectricalabuse.Storagepreferablyincool,dryandventilatedarea,whichissubjecttolittletemperaturechange.Storageathightemperaturesshouldbeavoided.Donotplacethebatterynearheatingequipment,norexposetodirectsunlightforlongperiods.OtherprecautionstopayattentiontoThebatterymayexplodeandburnifitisdisassembled,squeezed,ordirectlyplacedinfireorhightemperatureconditions.Donotshortcircuitorincorrectlyinstallthepositiveandnegativeterminalsofthebatteryinthedevice.OtherPrecautionsThebatterymayexplodeorcauseburns,ifdisassembled,crushedorexposedtofireorhightemperatures.Donotshortorinstallwithincorrectpolarity.8.Contactcontrol/personalprotectionExposurecontrols/personalprotectionrespiratoryprotectionWhenthebatteryventvalveisopened,theventilationequipmentshouldbeturnedonasmuchaspossibletoavoidlimitingthecellwiththeopenventvalvetoanarrowspace.Undernormaloperatingconditions,breathingprotectionisnotnecessary.RespiratoryProtectionIncaseofbatteryventing,provideasmuchventilationaspossible.Avoidconfinedareaswithventingcellcores.RespiratoryProtectionisnotnecessaryunderconditionsofnormaluse.atmosphericconditionsNotrequiredundernormalconditionsofuse.VentilationNotnecessaryunderconditionsofnormaluse.protectivegloveNotrequiredundernormalconditionsofuse.ProtectiveGlovesNotnecessaryunderconditionsofnormaluse.OtherprotectiveclothingorequipmentNotrequiredundernormalconditionsofuse.OtherProtectiveClothingorEquipmentNotnecessaryunderconditionsofnormaluse.PersonalprotectionshouldbetakenduringbatteryopeningvalvetestRespiratoryprotection,protectivegloves,protectiveclothingandsafetyglassshieldswithguardsareallrequired.PersonalProtectionisrecommendedforventingbatteryRespiratoryProtection,ProtectiveGloves,ProtectiveClothingandsafetyglasswithsideshields.ToprintDate:2022-11-229.PhysicalandchemicalpropertiesPhysicalandchemicalpropertiesShape:SquareAppearance:QuadrateshapeOdor:whenleaked,thereisthesmellofether.Odors:Ifleaking,smellsofmedicalether.pH:notapplicablepH:Notapplicableassupplied.Ignitionpoint:exceptfortheexposuretestofasinglecell,itisnotapplicable.FlashPoint:Notapplicableunlessindividualcomponentsexposed.Flammability:itisnotapplicableexceptfortheexposuretestofasinglecell.Flammability:Notapplicableunlessindividualcomponentsexposed.Relativedensity:itisnotapplicableexceptfortheexposuretestofasinglecell.Relativedensity:Notapplicableunlessindividualcomponentsexposed.Solubility(watersolubility):itisnotapplicableexceptforthesinglecellexposuretest.Solubility(water):Notapplicableunlessindividualcomponentsexposed.Solubility(other):Otherthanthesinglecellexposuretest,itisnotapplicable.Solubility(other):Notapplicableunlessindividualcomponentsexposed.10.StabilityandreactivityStabilityandreactivityStability:Theproductisstableundertheconditionsdescribedinsection7.Stability:ProductisstableunderconditionsdescribedinSection7.Conditionstobeavoided:heatingabove70orincineration.Deformation.Destruction.Crushing.Disassembly.Overcharging.Shortcircuit.LongexposureInhumidconditions.ConditionstoAvoid:Heatabove70orincinerate.Deform.Mutilate.Crush.Disassemble.Overcharge.Shortcircuit.Exposeoveralongperiodtohumidconditions.Avoidmaterials:oxidant,alkali,water.Materialstoavoid:Oxidisingagents,alkalis,water.Dangerousdecompositionproducts:toxicsmokeandpossibleformationofperoxides.HazardousDecompositionProducts:ToxicFumes,andmayformperoxides.Aggregatehazard:notapplicableHazardousPolymerization:N/A.Incaseofleakage,avoidcontactwithstrongoxidants,inorganicacids,strongbasesandhalogenatedhydrocarbons.Ifleaked,forbiddentocontactwithstrongoxidizers,mineralacids,strongalkalies,halogenatedHydrocarbons.Date:2022-11-2211.ToxicologicaldataToxicologicalinformationSignsandsymptoms:None,unlessthebatteryisbroken.Signs&symptoms:None,unlessbatteryruptures.Inthecaseofinternalexposure,steamsmokemayirritateeyesandskin.Intheeventofexposuretointernalcontents,vapourfumesmaybeveryirritatingtotheeyesandskin.Inhalation:Irritanttolungs.Inhalation:Lungiitant.Skincontact:skinirritation.Skincontact:Skinirritant.Eyecontact:Irritanttoeyes.Eyecontact:EyeirritantIngestion:Swallowingpoisoning.Ingestion:Poisoningifswallowed.Thehealthconditionwilldeteriorateinthefollowingcases:Incaseofcontactwiththeinternalmaterialofthebattery,minororsevereirritationmaycauseadryandburningsensationontheskin,anddamagethenervesofthetargetorgans(liver,kidney).Medicalconditionsgenerallyaggravatedbyexposure:Intheeventofexposuretointernalcontents,moderatetoserverirritation,burninganddrynessoftheskinmayoccur,TargetOrgansnerves,liverandkidneys.12.EcologicaldataEcologicalinformationEffectsonmammals:Unknownatpresent.Mammalianeffects:Noneknownatpresent.Ecologicaltoxicity:currentlyunknown.Eco-toxicity:NoneknownatpresentAccumulationinlivingorganisms:slowbiodegradation.Bioaccumulationpotential:SlowlyBio-degradable.Environmentalhazard:Therearenoknownenvironmentalhazards.Environmentalfate:Noneknownenvironmentalhazardsatpresent.13.DisposalofwasteDisposalconsiderationDonotburnorallowthebatterytemperaturetoexceed70,whichcanleadtoleakageand/orbatteryexplosion.Handleinaccordancewithlocalregulations.Donotincinerate,orsubjectcellstotemperatureinexcessof70,Suchabusecanresultinlossofsealleakage,and/orcellexplosion.Disposeofinaccordancewithappropriatelocalregulations/14.Date:2022-11-2214.TransportinformationTransportinformationTransportlabel:Class9dangerousgoodslabel,Labelforconveyance:Class9HazardLabel,UNnumber:UN3480UNNumber:UN3480Transportationspecificname:lithiumionbatterypack(includingpolymerlithiumionbattery)ProperShippingname:Lithiumionbatteries(includinglithiumionpolymerbatteries)Packaginglevel:IIPackagingGroup:SpecialprovisionsofIMDGcode:188,230,310,348,376,377,384,387IMDGCODESpecialprovisions:188,230,310,348,376,377,384,387EmSnumber:F-A,S-IEmSNo:F-A,S-IMarinepollutants:NoneMarinepollutant:NoHazardclassification:ThegoodsshallcomplywithIMDGCODE(Amdt.40-20)PackagingGuidelinesP903,includingtherequirementsoftheUN38.3testmanual.HazardClassification:ThegoodsshallbecompliedwiththePackingInstructionsP903ofIMDGCODE(Amdt.4020),includingthepassingoftheUN38.3test.Xonematch11entryDate:2022-11-2215.RegulatoryinformationRegulationinformationlegalinformaticsLawinformationRulesonDangerousGoodsDangerousGoodsRegulationsRecommendationsrelatingtothetransportofdangerousgoodsRecommendationsontheTransportofDangerousGoodsModelRegulationsInternationalMaritimeDangerousGoodsCodeInternationalMaritimeDangerousGoodsTechnicalDirectiveonSafeTransportofDangerousGoodsTechnicalInstructionsfortheSafeTransportofDangerousGoodsClassificationandNomenclatureofDangerousGoodsClassificationandcodeofdangerousgoodsOccupationalSafetyandHealthActOccupationalSafetyandHealthAct(OSHA)ToxicSubstancesControlActToxicSubstanceControlAct(TSCA)ConsumerProductSafetyActConsumerProductSafetyAct(CPSA)FederalPollutionControlActFederalEnvironmentalPollutionControlAct(FEPCA)OilPollutionActTheOilPolluti